Lead Isotopic Signature of the Hydrothermal Copper Mineralization in Drosh-Shishi Area, Chitral, Kohistan Arc Terrane, Northern Pakistan
Abstract
Copper mineralization in Drosh-Shishi area is a part of the upper crust of Kohistan arc terrane in Chitral, northern Pakistan. It is generally confined to the Gawuch formation in the area. This formation comprises of variably metamorphosed volcanics and sediments intruded by plutons of diorite and granodiorite. Copper mineralization is related to the hydrothermal activity and is mainly associated with altered diorites and quartz veins.
The lead isotopic ratios of three samples of galena from quartz veins in Drosh-Shishi area were determined. 206Pb/204Pb from 18.728 to 18.793, 207Pb/204Pb from 15.658 to 15.728 and 208Pb/204Pb from 39.040 to 39.285. These lead-isotopic ratios yield wide range of model ages of42 to 140 Ma. This mineralization is very young in terms of age and have values of 9.86 to 10.01. The studied galenas have comparable Pb-isotope ratios to that of Rossie-Type veins of USA and Canada and are more radiogenic to the conformable massive sulfides and less radiogenic to Mississippi Valley-Type sulfide deposits. The Lead isotopic data further suggest that the lead in galena may have been derived from the arc volcanics or pelagic sediments of ocean crust of Neo-Tethys or continental crust of Indian plate and may have relation with orogeny.
References
Ayuso, R. A., 1986. Lead-isotope evidence for distinct source of Granite and for distinct basement in the northern Appalachians, Econ. Geol. 14(4), 332-325.
Deb. M., Thorpe, R. I, Cumming, G. L. & Wagner, P., 1989. Age, source and stratigraphic implications of Pb isotope Data for Conformable, sediment hosted, Base metal Deposits in the Proterozoic Aravalli-Delhi Orogenic belt, Northwestern India. Precamb. Res. 43, 1-22.
Doe, B. R. & Zartman, R. E., 1979. Plumbotectonics 1 the phanerozoic. In: Geochemistry of hydrothermal ore deposits (H.L. Barnes, ed.). Holt, Rinehart and Winston, New York, 22-70.
Doe, B. R, & Delevaux, M. H., 1972. Source of lead in south east Missouri galena Ores: Econ. Geo. 67, 409-425.
Faure, G., 1986. Principles of Isotope Geology (second edition). John Wiley & Sons, New York, 589.
Fletcher, I. R., 1979. A Lead isotope study of Lead-Zinc mineralization associated with the Central Metasedimentary belt of Grenville Province. Ph.D. Thesis, Univ. Toronto, 165.
Fletcher, I. R. & Farquhar, R. M., 1982. The Protocontinental nature and regional variability of central metasedimentary belt of the Grenville province. Lead isotope evidence. Canad. Jour. Earth Sci. 19, 239-253.
Gulson, B. L., Perkins, W. G., & Mizon, K. J., 1983. Lead isotope studies bearing on genesis of copper orebodies at Mount Isa, Queeniand. Econ. Geol. 78, 1466-1504
Gulson, B. L., 1984. Uranium- lead and lead continental crust of Indian plate. investigations of minerals from the Broken Hill lodes and mine sequence rocks. Econ. Geo. 79, 476-490.
Gulson, B. L., 1985. Shale-hosted lead-Zink deposits in Northern Australia: Lead isotope variations. Econ. Geol. 80, 2001-2012.
Heyl, A. V., Delevaux, M. H., Zartman. R. E. & Brock, M. R., 1966. Isotopic study of galenas from upper mississippi Valley, The illinnoise-Kentucky and some Appalachian Valley minerals districts: Econ. Geol. 69, 992-1006.
Khan, T., Khan, M. A. & Jan, M. Q., 1994. Geology of a part of the Kohistan terrane between Gligit and Chilas, northern areas, Pakistan. Geol. Bull. Univ. Peshawar, 27, 99-112.
Koeppel, V., 1980. Lead- isotope studies of strdtiform ore deposits of Namaqualand, NW Cape Province, South Africa and their implications on the age of the Bushmaniand sequence. Proceedings of the fifth quadrennial International Association on the Genesis of ore deposits Symposium, Schweizerbart, sche Verlagsbuch-handlung Stuttgart, 195-207.
LeCouteur, P.C., 1973. A study of lead isotope from mineral deposits in Southeastern British Columbia and in the Anvil Range, Yukon Territory. Unpubl. Ph.D. thesis. Univ. South. Carol. Columbia.
Petterson, M. G. & Windley, B. F., 1985. Rb-Sr dating of the Kohistan arc batholith in the Trans Himalaya of N. Pakistan and tectonic implications. Earth Planet. Sci. Letters, 74, 54-75.
Pudsey, C. J., 1986. The northern suture, Pakistan: Margin of a Cretaceous island arc. Geol. Mag. 123, 405-423.
Pudsey, C. J., Coward, M. P., Luff, L. W., Shackelton, R. M., Windley, B. F. & Jan, M. Q., 1985. Collision zone between the Kohistan arc and the Asian plate in NW Pakistan. Transactions of Royal Society, Edinburgh, Earth Sciences 76, 463-479.
Richards, J.R., 1981. Some thoughts on the time-dependence of lead isotope ratio. Geochemistry international, 1981, 17-36.
Shah, M. T. & Hamidullah, S., 1994. Field and Mineralogy constraints of the Dir Metavoicanic Sequence, Kohistan arc Terrane Northern Pakistan. Geol. Bull. Univ. Peshawar, 27, 43-55.
Shah, M. T., Shervais, J. W. & Ikramuddin, M., 1994. The Dir metavoicanic sequence. calc-alkaline magmatism within the Kohistan arc terrane, northern Pakistan. Geol. Bull. Univ. Peshawar, 27, 9-27.
Shah, M. T., Thorpe, R. L, Siddique, S. A., 1992. Lead isotope signature of the Proterozic sediment- hosted base metal deposits at the margin of the Indian plate in Besham area, northern Pakistan. Geol. Bull. Univ. Peshawar, 25, 59-65.
Stacey, J. S. & Kramers, J. D., 1975. Approximation of terrestrial lead isotope evolution by two -stage model. Earth and Planetary Science Letters, 26, 207-221.
Sullivan, M. A., Windley, B. F., Saunders, A. D., Haynes, J. R. & Rex, D. C., 1993. A Paleogeographic reconstruction of the Dir group. Evidence for magmatic arc migration within Kohistan N. Pakistan. In: Himalayan Tectonic (P. J. Treloar, & M. P. Searle, eds.) Geol. Soc. London, Spec. Pub. 42, 313-345.
Tahirkheli, R.A.K., Mattaur, M., Proust, F. & Tapponier, P., 1979. The India-Eurasia Suture zone in northern Pakistan: Some new data for the interpretation at plate scale. In: Farah, A. & DeJong, K.A., (Eds.) Geodynamics of Pakistan. Geological Survey of Pakistan, Quetta, 125-130.
Treloar, P. J., Rex, D. C., Guise, P. G., Coward, M. P., Searle, M. P., Windley, B, F., Petterson, M. G., Jan, M. Q. & Luff, I., 1989. K-Ar and Ar-Ar geochronology of the Himalayan collision in NW Pakistan, constraints on the timing of suturing, deformation, metamorphism and uplift. Tectonics, 4, 881-909.
Zartman, R. E. & Doe, B. R., 1981. Plumbotectonics - the model. Tectonophysics, 75, 135-162.
Zeitler, P. K., 1985. Cooling history of the NW Himalaya, Pakistan. Tectonics, 4, 127-151.