Mineral chemistry of pyrite by EPMA mapping from the Senjedeh Gold deposit, Iran
Keywords:
Pyrite, EPMA, Senjedeh, Gold, Mineral chemistryAbstract
The Senjedeh gold deposit is situated 60 km southwest of Delijan in the central section of Sanandaj-
Sirjan metamorphic belt. Most of rocks in this region have undergone greenschist to lower amphibolite
metamorphism. The gold mineralization in the study area occurs as quartz sulfide veins in metarhyolite host
rock. In order to detect the abundance of gold and associated elements in the pyrite using the techniques of
mineralogical studies, electron probe microanalysis (EPMA) and back-scattered imaging through thin and
polished sections in the Senjedeh gold deposit. Two generations of pyrite recognised: first generation, being
anhedral to subhedral, (G1) are oriented along foliation contain high to medium gold content(up to 810ppm),
shows deformed and fractured character. The second generation of pyrite (G2) is euhedral with medium to
low gold content (below limit of detection up to 110ppm). According to electron back-scattered image and
EPMA data, the presence of gold mainly occurs as submicroscopic-microscopic inclusions and invisible
particles in microfractures of pyrite. Also based on EPMA mapping it is concluded that first-generation of
pyrites contain high level of cobalt which could be a good indication of the presence of mafic and ultramafic
rocks as a source of hydrothermal solutions compared to felsic rocks and consistent with orogenic gold
deposit.
References
Agangi, A, Przybyłowicz, W. Hofmann, A., 2015. Trace element mapping of pyrite from Archean gold deposits – A comparison between PIXE and EPMA, Nuclear Instruments and Methods in Physics Research Section. Beam Interactions with Materials and Atoms 348, 302-306.
Alavi, M., 2004., Tectonics of the Zagros orogenic belt of Iran: new data and interpretation. Tectonophysics, 229, 211- 238.
Alavi, M., 2004., Regional stratigraphy of the Zagros fold-thrust belt of Iran and its proforeland evolution. American Journal of Science, 304, 1–20.
Alipour-Asll, M., 2018., Geochemistry, fluid inclusions and sulfur isotopes of the Govin epithermal Cu-Au mineralization, Kerman province, SE Iran. Gexplo, 196, 156-172.
Aliyari, F., Rastad, E., & Mohajel, M., 2012. Gold Deposits in the Sanandaj–Sirjan Zone: Orogenic Gold Deposits or Intrusion- Related Gold Systems. Resource Geology, 62, 296–315.
Almasi, A., Yousefi, M., & Carranza, E.J.M., 2017. Prospectivity analysis of orogenic gold deposits in Saqez-Sardasht Goldfield, Zagros Orogen, Iran. Ore Geology Reviews, 91, 1066-1080.
Amponsah, P., Salvi, S., Didier, B., Baratoux, L., Siebenaller, L., Jessell, M., Mackenzie Nude, P., & Gyawub, E A., 2016. Multistage gold mineralization in the Wa-Lawra greenstone belt, NW Ghana: The Bepkong deposit. Journal of African Earth Sciences, 120, 220-237.
Cook, N., Coibanu, C., Mao, J., 2009. Textural control on gold distribution in As-free pyrite from the Dongping, Huangtuliang and Hougou gold deposits, North China Craton (Hebei Province, China). Chemical Geology, 264(1), 101-121
Farhan, M., Arif, M., Ying, Y., Chen, X., Garbe- Schönberg, G., Li, C., Hussain, Z., Ullah, Z., Zhang, P., Khan, A., 2021. Fluid source, element mobility and physicochemical conditions of porphyry-style hydrothermal alteration-mineralization at Mirkhani, Southern Chitral, Pakistan, Ore Geology Reviews, 135. doi.org/10.1016/j.oregeorev.2021.104222.
Fougerouse, D., Reddy, S., Aylmore, M., Yang, L., Guagliardo, P., Saxey, D., Rickard, W., Timms, N., 2021. A new kind of invisible gold in pyrite hosted in deformation-related dislocations, Geology, doi.org/10.1130/G49028.1.
Li, Z., Zhu, X., Lu, H., & Han, T., 2013. The occurrence of gold in pyrite from the Liulincha gold ore belt, western Hunan Province, China. China Journal Geochemistary, 32, 392–397.
Masoudy, F., 1997. Contact metamorphism and pegmatite development in the region SW of Arak, Iran, Ph.D. thesis, university of leeds, Uk.
Mohajjel, M., Fergusson, C L., & Sahand, M.R., 2003., Cretaceous-Tertiary convergence and continental collision, Sanandaj-Sirjan zone, western Iran. Journal of Asian Earth Sciences, 21, 397-412.
Morishita, Y., Shimada, N., & Shimada, K., 2018., Invisible gold in arsenian pyrite from the high-grade Hishikari gold deposit, Japan: Significance of variation and distribution of Au/As ratios in pyrite. Ore Geology Reviews, 95, 79-93.
Steven, M., Robert, R., & Hough, M., 2013., Microstructural evolution and trace element mobility in Witwatersrand pyrite. Contrib. Mineral Petrol., 166, 1269–1284.
Wan, B., Yang, W., Deng, C., & Xiao, C., 2018. Rb- Sr geochronology of single gold-bearing pyrite grains from the Katbasu gold deposit in the South Tianshan, China and its geological significance. Ore Geology Reviews, 100, 99-110.