Hydrocarbon source rock potential of the Early Permian rocks in the Potwar Basin, Salt Range, Pakistan
Keywords:
Hydrocarbon, Lower Permian, Thermal maturity, Potwar basinAbstract
In this paper the hydrocarbon source rock potential of the Early Permian strata of the Choa-Khewra Road Section in eastern Salt Range and the Zaluch Nala Section in western Salt Range, Potwar Basin, Pakistan is presented. The six outcrop samples of organic clays from the Tobra and Dandot Formations from eastern Salt range while Warchha and Sardhai Formations from the Zaluch Nala sections were collected for the Total Organic Carbon (TOC) and Rock Eval Pyrolysis analyses. Various geochemical cross plots were constructed using the total organic carbon and pyrolysis values of the analyzed rock samples to know the qualitative assessment of organic matter and presence of any indigenous or migrated hydrocarbons. Our result shows that the Tobra Formation is thermally mature with 0.55 % and 0.83 % TOC hence Type III kerogen with a tendency to generate indigenous hydrocarbons. The Dandot Formation is thermally immature Type III kerogen, with 0.78 % TOC that can generate indigenous hydrocarbons. The Warchha and Sardhai formations both are thermally immature Type III kerogen and a 0.73 %; 1.05 % and 1 % respectively, with an indigenous hydrocarbons generation potential. The XRD results shows that the percentage of clay minerals i.e. ductile minerals are less than the brittle minerals i.e. Quartz etc. Brittleness Index for the Tobra, Dandot and Warchha Formations shows brittle nature and are suitable for hydraulic fracturing while the Sardhai formation shows less brittle material and considered suitable for fracking
References
Ahmad, S., Ullah, M., Ullah, S., Khan, S., Khan, Y., Jan, I. U., Rehman, K., Mohibullah, M., Attaulllah, Jan, S., 2018. Stratigraphic and Paleoclimatic Reconstruction of the Upper Carboniferous-Lower Permian strata from the Southern Gondwanaland remnants in Pakistan, Stratigraphy, 15 (2), 69–90.
Bacon, C. N., Calver, C. R., Boreham, C. J., Lenman, D. E., Morrison, K. C., Revill, A. T., Volkman, J. K., 2000. The petroleum potential of onshore Tasmania: a review. Geological Survey Bulletin, 71 (1), 93.
Baker, D. M., Lillie, R. J., Yeats, R. S., Johnson, G. D., Yousuf, M., Zamin, A. S. H., 1988. Development of the Himalayan frontal thrust zone-Salt Range, Pakistan. Geology, 16, 3-7.
Behar, F., Beaumont, V., Penteado, H. L., De, B., 2001. Rock-Eval 6 technology: performances and developments. Oil & Gas Science and Technology, French Institute of Petroleum, 56 (2), 111-134.
Bjorlykke, K., Avseth, P., 2010. Petroleum geoscience: From sedimentary environments to rock physics. Berlin, Springer. Bordenave, M. L., 1993. Applied Petroleum Geochemistry. Editions Technip, Paris.
Coward, M. P., Windley, B. F., Broughton, R., Luff, I. W., Petreson, M., Pudsey, C. J., Rex, D. Asif, K. M., 1986. Collision tectonics in the NW Himalayas, Special Publication, the Geological Society London, 19, 203-219.
Demaison, G. J., Moore, G., 1980. Anoxic environments and oil source bed genesis, American Association of Petroleum Geologists Bulletin, 64 (8), 1179–1209.
Dembicki, J., 2009. Three common source rock evaluation errors made by geologists during prospect or play appraisals. American Association of Petroleum Geologists Bulletin, 93 (3), 341-356.
Dow, W. G., 1977. Kerogen studies and geological interpretations. Journal of geochemical Exploration, 7, 79-99 Dyman, T. S., Palacas, J. G., Tysdal, R. G., 1996. Source rock potential of middle cretaceous rocks in southwestern Montana. American Association of Petroleum Geologist Bulletin, 80, 1177- 1184.
Eble, C., John, H., David, H., Michele, C., John R., 2015. Source rock geochemistry. In Patchen, D. G., Carter, K. M., (Eds.), A geologic play book for Utica Shale Appalachian basin exploration, Final report of the Utica Shale Appalachian basin exploration consortium, 102-141.
Espitaliè, J., 1986. Use of Tmax as a maturation index for different types of organic matter, comparison with vitrinite reflectance; Thermal modelling in sedimentary basins, Burrus, Journal Editions Technip, Paris, 475–96.
Gee, E. R., 1981. Pakistan Geological Salt Range Series (6 sheets, Scale 1:50000) Directorate of the overseas survey, United Kingdom, For the Government of Pakistan and Geological survey of Pakistan.
Ghazi, S., Mountney, N. P., Butt, A. A., Sharif, S., 2012. Stratigraphic and palaeoenvironmental framework of the Early Permian sequence in the Salt Range, Pakistan. Journal of Earth system science, 121 (5), 1239-1255.
Ghori, K. A. R., 1998. Petroleum Source-Rock Potential and Thermal history of the Officer Basin, Western Australia, Western Australia Geological Survey, 52.
Ghori, K. A. R., 2002. Modeling the hydrocarbon generative history of the Officer Basin, Western Australia. Petroleum Exploration Society of Australia Journal, (29), 29–42.
Hunt, J. M., 1996. Petroleum Geochemistry and Geology, Second edition, W. H. Freeman and Company, New York, 734. Hussain, B. R., 1967.
Saiduwali Member, a new name for the lower part for the Permian Amb Formation, West Pakistan. University Studies (Karachi), Science and Technology, 4 (3), 88-95.
Jamil, A., Waheed, A., Sheikh, R. A., 2009. Pakistan's major petroleum plays-An Overview of Dwindling Reserves. Search and Discovery, Article, (10399), 1-2.
Jan, I. U., Stephenson, M. H., 2011. Palynology and correlation of the Upper Pennsylvanian Tobra Formation from Zaluch Nala, Salt Range, Pakistan. Palynology, 35 (2), 212–225.
Jan, I. U., Stephenson, M. H., Khan, F. R., 2009. Palynostratigraphic correlation of the Sardhai Formation (Permian) of Pakistan. Review of Palaeobotany and Palynology, 158, 72-82.
Jan., U. I., Iqbal, S., Davies, S. J., Zalasiewicz, J. A., Stephenson, M. H., Wagreich, M., Haneef, M., Hanif, M., Ahmad, S., 2017. A Periglacial Palaeoenvironment in the Upper Carboniferous-Lower Permian Tobra Formation of the Salt Range, Pakistan. Acta Geologica Sinica, 91(3), 1063-1078.
Jan., U. I., Shah, A., Stephenson, M. H., Iqbal, S., Hanif, M., Wagreich, M., Hussain, H. S., 2016. The sedimentology of the Lower Permian Dandot formation: A component of the Gondwana deglaciation sequence of the Salt Range, Pakistan. Rivista Italiana di Paleontologia e Stratigrafia, 122 (1), 75-90.
Jarvie, D. M., 1991. Total organic carbon (TOC) analysis. Merrill RK Source and migration processes and evaluation techniques. American Association of Petroleum Geologist Bulletin, Treatise of Petroleum Geology, Handbook of Petroleum Geology, 113–118.
Jarvie, D. M., Brenda, L. C., Floyd, H., John, T. B., 2001. Oil and Shale Gas from the Barnett Shale, Ft. Worth Basin, Texas; National Convention, Denver, CO, American Association of Petroleum Geologist Bulletin, 13, 85.
Jarvie, D. M., Hill, R. J., Ruble, T. E., Pollastro, R. M., 2007. Unconventional Shale Gas Systems. The Mississippian Barnett Shale of North-Central Texas as one Model for Thermogenic Shale-Gas Assessment, American Association of Petroleum Geologist Bulletin, 91 (4), 475- 499.
Jaume, S. C., Lillie, R. J., 1988. Mechanics of the Salt Range-Potwar Plateau, Pakistan: a fold-and thrust belt underlain by evaporates, Tectonics, 7, 57-71.
Johannes, J., Kruusement, K., Palu, V., Veski, R., Bojesen, J. A., 2006. Evaluation of oil potential of Estonian Shales and Biomass samples Using Rock-Eval Analyzer, Oil Shale, 23 (2), 110-118.
Kazmi, A. H., Rana, R. A., 1982. Tectonic map of Pakistan at a scale of 1:2,000,000. Geological Survey of Pakistan, 1 sheet.
Krishnan, M. S., 1960. Geology of India and Burma. Madras: Higgnbothams (Private) Ltd, 604.
Kusskaraa, V. A., 2013. Technically Recoverable Shale Gas and Shale Oil Resources: An Assessment of 137 Shale Formations in 41 Countries outside the United States.
Law, C., 1999. Evaluating source rocks. In: Foster, N., Beaumont, E, A., (Eds.), Treatise of the handbook of petroleum geology. American Association of Petroleum Geologists, Tulsa, Oklahoma, 6 (1), 6-41.
Le Fort, P., 1975. Himalaya: the collided range; Present knowledge of the continental arc. American Journal of Science, 275A, 1-44.
Linley, K. A., 2014. User Guide for the Vitrinite Reflectance dataset. British Geological Survey open report, OR/14/055. 13.
Magoon, L. B, Dow, W. G., 1994. The petroleum system-from source to trap, American Association of Petroleum Geologists, Memoir 60.
Mani, D., Dayal, A. M., Patil, D. J., Hafiz, M., Hakoo, N., Bhat, G. M., 2014. Gas potential of proterozoic and phanerozoic shales from NW Himalaya, India: inferences from pyrolysis. International Journal of Coal Geology, 128-129, 81-95.
Mertmann, D., 1999. Das marine Perm in der Salt Range und Trans Indus Ranges, Pakistan. Berliner Geowissenschaftliche Abhandlungen, A204, 1-94.
Mohamed, M. N., Fatma, S. R., Mahmoud, M. H., Nira, M. L., 2015. Evaluation of organic matters, hydrocarbon potential and thermal maturity of source rocks based on geochemical and statistical methods: Case study of source rocks in Ras Gharib oilfield, central Gulf of Suez. Egypt. Egypt Journal of Petroleum, 24, 203–211.
Mukhopadhyay, P. K., Dow, W. G., 1994. Vitrinite reflectance as a maturity parameter. Vitrinite reflectance as a maturity parameter, 570, 1-24.
Noetling, F., 1901. Beitrage zur Geologie der Salt Range, insbesondere der permichem und triasuchen Ablagerungen. Ucucs Jahrb. Mineral. Bcilagc-Band, 14, 369- 471.
Peters, K. E., Cassa, M. R., 1994. Applied source rock geochemistry, American Association of Petroleum Geologist Memoir. Pettijohn, F. J., 1984. Sedimentary Rocks, 3rd edition, Harper and Raw Publisher, USA.
Potter, P. E., Mayand, J., Pryor, W. A., 1980. Sedimentology of shale; Springer Verlag, New York, Heidelberg, Berlin.
Rodriguez, N. D., Philp, R. P., 2010. Geochemical characterization of gases from the Mississippian Barnett Shale, Fort Worth Basin, Texas. American Association of Petroleum Geologist Bulletin, 94 (11), 1641-1656.
Schlesinger, W. H., 1977. Carbon balance in terrestrial detritus, The Annual Review of Ecology, Evolution, and Systematics, 8, 51–81.
Seeber, L., Armbruster, J. G., Quittmeyer, R. C., 1981. Seismicity and continental subduction in the Himalayan arc. Zagros Hindu Kush Himalaya Geodynamic Evolution, 215-242.
Selley, R. C., 1985. Elements of Petroleum Geology. W. H. Freeman and Company, New York. 449.
Shah, A., Haneef, M., Hanif M., Jan, U. I., 2010. Lithofacies and palaeoenvironmental analysis of Carboniferous-Permian Nilawahan Group, Salt Range Pakistan. Pakistan Journal of Hydrocarbon Research, 20, 49-52.
Shah, J., Jan, M. R., Zeeshan, M., Imran, M., 2017. Kinetic equilibrium and thermodynamic studies for sorption of 2, 4-dichlorophenol onto surfactant modified fuller's earth, Applied Clay Science, 143, 227-233.
Shah, S. M. I., 2009. Stratigraphy of Pakistan. Government of Pakistan Ministry of Petroleum and Natural Resources, Geological Society of Pakistan, 22, 20-188.
Stein, 2007. Upper Cretaceous/lower Tertiary black shales near the North Pole: Organic- carbon origin and source rock potential. Marine Petroleum Geology, 24, 67–73.
Stephenson, M. H., Jan, I. U., Al-Mashaikie, S. Z. A. K., 2013. Palynology and correlation of Pennsylvanian glacigene rocks in Oman, Yemen and Pakistan. Gondwana Research, 24, 203–211.
Tabatabaei, H., 2017. Potential Evaluation and Basin Modeling of the Pabdeh Formation in Zagros Basin: A Case Study, Open Journal of Geology, 7, 505-516.
Teichert, C., 1967. Nature of Permian glacial record. Salt Range and Khisor Range, West Pakistan. Ncucs Johrb, Geol. Palacont., Abh., 129 (2), 167-184.
Tissot, B. P., Welte, D. H., 1978. Petroleum Formation and Occurrence: A New Approach to Oil and Gas Exploration. Berlin, Heidelberg, New York: Springer- Verlag. ISBN 3 540 08698 6.
Tissot, B. P., Welte, D. H., 1984. Petroleum Formation and occurrence: A new approach to oil and gas exploration; 2nd ed.: Springer Verlag, Berlin, 150-169.
Tissot, B. P., Welte, D. H., 1985. Petroleum Formation and Occurrence. Eos, Transactions American Geophysical Union Second, Springer-Verlag, Berlin, 66.
Van-Krevelen, D. W., 1961. Coal typology–chemistry–physics-constitution, 1st ed. Elsevier, The Netherlands.
Varma, A. K., Hazra, B., Srivastava, A., 2014. Estimation of total organic carbon in shales through color manifestations, Journal of Natural Gas Science and Engineering, 18, 53–57.
Wang, G., 2013. Organic-rich Marcellus shale lithofacies modeling and distribution pattern analysis in the Appalachian Basin; American Association of Petroleum Geologist Bulletin, 97 (12), 2173–2205.
Wardlaw, B. R., Pogue, K. R., 1995. The Permian of Pakistan. In the Permian of Northern Pangea, Springer, Berlin, Heidelberg. 215-224.
Yeats, R.S., Lawrence, R.D., 1984. Tectonics of the Himalayan thrust belt in northern Pakistan. In: Haq, B. U., Milliman, J. D., (Eds.), Marine Geology and oceanography of Arabian sea and coastal Pakistan. Van Nostrand Reinhold Co., New York, 177-200.