Mineralogical and beneficiation studies of the Fe-Cu ores of Dammal Nisar, Chitral, NW Himalayas Pakistan
Keywords:
Iron and copper ores; skarn mineralogy; beneficiation; Dammal Nisar; Chitral.Abstract
Medium-grade iron and copper ore deposits occur in the Dammal Nisar area of southern Chitral, NW Pakistan. They are distributed as 20 to 200m2 size lens-shaped bodies in the metavolcanic and metasedimentary rocks of the Gawuch Formation along the eastern contact of the arc–related Mirkani granitoids. Detailed mineralogical investigation using petrographic, X-ray Diffraction and SEM-EDX techniques shows that these deposits consist of magnetite, hematite and malachite as the principal ore minerals while occasional chalcopyrite and pyrite are also observed. Quartz, garnet, olivine, epidote, calcite, pectolite, serpentine and foshagite occur as the associated gangue phases. Two main paragenetic stages can be recognized in these deposits based on petrographic and field observations. Olivine and garnet represent the prograde skarn mineralogy while retrograde mineral assemblage is characterized by epidote, amphibole and serpentine. On the basis of proximity to the Mirkani granitoids and prograde and retrograde skarn mineralogy, the studied ore bodies may be classified as skarn-type magnetite deposits.
Being medium-grade in their current form, different beneficiation techniques including gravity separation, magnetic separation and froth flotation were employed to assess the up-gradation potentials of the Dammal Nisar ores. The results reveal that an average Fe2O3 concentrate of 89.15 wt. % at 48% recovery and 90.7 wt. % at 55% recovery are obtainable through a combination of gravity and magnetic separation techniques after sample feeds with 72-75 wt. % Fe2O3 contents are pulverised at 20 and 25 minutes, respectively. As such, the studied ores can be utilized in steel manufacturing. Furthermore, average product of 1.91 and 5.55 wt. % Cu is obtainable through froth flotation, from the studied ore samples showing 0.28 to 0.68 wt. % Cu. Besides, more than 60% of the samples grain size is reduced to <106 microns, when subjected to a grinding interval of up to 25 minutes thereby enhancing liberation of ores from their associated gangue phases. The better liberation results in a relatively higher recovery of both iron and copper minerals.
References
Abbas, S.G., Kakepoto, A., Ahmad, M.H., 1998. Iron ore deposits of Dilband area Mastung District, Qalat Division, Baluchistan. Geological Survey of Pakistan, Unpublished report.
Ahmad, Z., 1969. Directory of mineral of deposits of Pakistan. Geological Survey of Pakistan, Record,15, 3, 220.
Ali S.T., 1963. Iron ore resources of Pakistan. CENTO Symposium, Iron Ore, Isphahan, 55-60.
Asrarullah, 1978. Iron ores of Pakistan. CENTO symposium on industrial rocks and minerals, Lahore, 303-313.
Aslam, M., Khan, A., Ashraf, M., 2007. Geology and Mineral resources of Chitral District, NWFP, Pakistan. Records, Geological Survey of Pakistan, 126.
Austromineral, 1978. Final study (Feasibility report), Mineral exploration and mining development, Chitral District: Submitted to Sarhad Development Authority, Peshawar, Pakistan. Austromineral, Vienna, Austria, 1-289.
Bard, J. P., 1983. Metamorphism of an obducted island arc: Example of the Kohistan sequence (Pakistan) in the Himalayan collided range. Earth Planetary Science Letters, 65, 133-144.
Bignold, S.M., Treloar P.J., 2003. Northward subduction of the Indian Plate beneath the Kohistan island arc, Pakistan Himalaya: New evidence from isotopic data. Journal of Geological Society of London, 160 (3), 377-384.
Coward, M.P., Butler, R.W.H., Khan, M.A., Knipe R.J., 1987. The tectonic history of Kohistan and its implications for Himalayan structure. Journal of Geological Society of London 144, 377–391.
Coward, M.P., Windley, B.F., Broughton, R.D., Luff, I.W., Petterson, M.G., Pudesy, C.J., Rex, D.C., Asif, K.M., 1986. Collision tectonics in the NW Himalaya. In: Coward, M.P., Ries, A. (Eds.), Collision tectonics. Geological Society of London Special Publication, 19, 203–219.
Fletcher, C.J.N., 1985. Copper mineralization in Kohistan Complex near Dir and Drosh, North West Frontier Province. British Geological Survey Circular, 65.
Haq, E., Khan, M.A., Paracha, M.H., Afridi, A.G. K., 2006. Geological map of Mirkhani quadrangle, District Chitral, NWFP, Pakistan. Map series, Geological Survey of Pakistan.
Huebergeri, S., Schaltegger, U., Burgi, J. P., Villa, I.M., Frank, M., Dawood, H., Hussain, S.,
Zanchi., 2007. Age and isotopic constraints on magmatism along then Karakoram- Kohistan. NW Pakistan: Evidence for subduction and continued convergence after India-Asia collision. Swiss Journal of Geoscience, 24. doi:10.1007/s00015-007-1203-7.
Hussain, A., Karim, T., 1993. Mineral Map of North West Frontier Province, Geological Survey of Pakistan, special Publication.
Jagoutz, O., Muentener, O., Schmidt, M.W., Burg, J.P., 2011. The respective roles of flux and decompression melting and their relevant liquid lines of descent for continental crust formation: Evidence from the Kohistan arc. Earth Planetary Science Letters, 303, 25-36.
Kazmi, A.H., Abbas, S.G., 2001. Metallogeny and Mineral deposits of Pakistan. Graphic Publishers, Karachi, 5.
Kazmi, A.H., Jan, M.Q.,1997. Geology and Tectonics of Pakistan. Graphic Publishers, Karachi, 5.
Khan, M.A., Stern, R.J., Gribble, R.F., Windley, B.F., 1997. Geochemical and isotopic constraints on subduction polarity, magma sources, and paleogeography of the Kohistan intra-oceanic arc, Northern Pakistan Himalaya. Journal of Geological Society of London, 154 (6), 935–946.
Kidwi, A.H., Imam, S.A., 1958. Magnetite deposits of Dammal Nisar, Chitral Stat: (West Pakistan); GeoIogical Survey of Pakistan, Information, 7.
Meinert, L.D., Dipple., G.M., Nicolescu, S., 2005. World skarn deposits. In: Hedenquist, J.W., Thompson, J.F.H., Goldfarb, R.J., Richards, J.P. (Eds.), Economic Geology 100th Anniversary Volume. Society of Economic Geologists, 299–33.
Metso., 2006. Basics in Minerals Processing, 5th Edition, Section 4 – Separations, Metso Minerals Corporation.
Miller, D.J., Loucks, R.R., Ashraf, M., 1991. Platinium-group elements mineralization in the Jijal layered ultramafic-mafic complex, Pakistan Himalaya Econmic Geology, 86, 1093-1102.
Mulaba, A.F., Bell, D.T., 2005. Some aspects of laboratory flotation of Copper- C o minerals from mixed oxide ores, The South African IMM. 3rd Southern African conference, Base Metals, Proceedings, 191-200.
Petterson, M.G., Windley, B.F., 1985. Rb-Sr dating of the Kohistan arc- batholith in the Trans-Himalaya of north Pakistan and tectonic implications. Earth and Planetary Science. Letters, 74, 45-57.
Petterson, M. G., Wi n d l e y, B. F., 1986. Petrological and geochemical evolution of the Kohistan arc batholith, Gilgit, Northern, Pakistan. Geological Bulletin University of Peshawar, 19, 121–149.
Pudsey, C.J., Coward, M.P., Luff, I.W., Shackleton, R.M., Windleyb, F., Jan, M.Q., 1985. The collision zone between the Kohistan arc and the Asian plate in NW Pakistan. Transactions of the Royal Society of Edinburgh, Earth Sciences, 76, 464–479.
Searle, M.P., Khan, M.A., Fraser, J.E., Gough, S.J., Jan, M.Q., 1999. The tectonic evolution of the Kohistan-Karakoram collision belt along the Karakoram Highway transect, North Pakistan. Tectonics, 18, 929-949.
Tahirkheli, R.A.K., 1979. Geology of Kohistan and adjoining Eurasia and Indo-Pakistan continents, Pakistan. Geological Bulletin of University of Peshawar, 11, 1–30.
Tahirkheli, R.A.K., 1982. Geology of the Himalaya, Karakoram and Hindukush in Pakistan. Geological Bulletin of University of Peshawar, Special Issue, 15, 1–51.
Tahirkheli, T., Shah, M.T., Tahseenullah, K., Khan, M. A., 1996. Fluid inclusions studies of the cupper bearing quartz veins in Gawuch formation in Drosh-Shishi Valley area, Chitral, Northern Pakistan. Geological Bulletin of University of Peshawar, 29, 51-57.
Tahirkheli, T., Shah M.T., Khan M.A., Bilqees, R., 2012. Mineralogy and geochemistry of diorites and associated hydrothermal sulfide mineralization of Gawuch Formation in Drosh area, Chitral, northern Pakistan. Journal of Himalayan Earth Sciences, 45(1), 31-52.
Treloar, P.J., Broughten, R.D., Coward, M.P., Williams, M.P., Windley, B.F., 1989. Deformation, metamorphism and imbrication of the Indian plate south of MMT, North Pakistan. Journal of Metmorphic Geology, 7, 111-127.
West Pakistan Industrial Development Corporation (WIPDC), 1970. Mineral resources of North West Frontier Province. Unpblished Report, 120.
Zahid, M., Arif, M., Moon., C.J., 2013. Petrogenetic implications of the mineral- chemical characteristics of scheelite and associated phases from Miniki Gol (Chitral), North West Pakistan. Geoscienc Journal, 17 (DOI 10.1007/s12303-013-0035-x) (4), 403– 416.