The platinum-group element geochemistry of chromitites and silicate rocks from Swat, northwestern Pakistan
Abstract
The concentrations of the Platinum-group elements (PGE) and Au were determined in a limited number of samples which represent chromitites, altered ultramafic and mafic rocks of the Swat valley ophiolite. The PGE characteristics of the chromitites mostly conform to the trend exhibited by the podiform chromitites. However, being sulphide-poor and containing Cr-rich chromite, the Pd content of one of the samples is anomalously high compared to similar chromitites from other areas. This enrichment in Pd is probably caused by a localized hydrothermal activity. The Ir content of the chromite-poor, altered ultramafic rocks is remark- ably uniform (4 ppb) and close to the values in mantle materials but their Pd (10 ± 3.7 ppb) and Au (5 ± 3.5 ppb) abundances are distinctly higher than the latter. These features of PGE and Au concentration of the host ultramafic rocks are consistent with an origin involving partial melting followed by hydrothermal alteration.
References
Arif, M., 1994. Studies of ultramafic rocks from Swat, northwestern Pakistan: Implications for the genesis of emerald and nickeliferous phases. Unpubl. Ph.D Thesis, University of Leicester, UK.
Bacuta, G. C, Kay, R. W., Gibbs, A. K. & Lipin, B. R., 1990. Plantinum-group element abundance and distribution in chromite deposits of the Acoje Block, Zambales ophiolite complex, Philippines. Jour. Geochem. Expl., 37, 113-145.
Barnes, S. J. & Picard, C. P., 1993. The behaviour of plantinum-group elements during partial melting, crystal fractionation, and sulphide segregation: an example from the Cape Smith Fold Belt, northern Quebec. Geochim. Cosmochim. Acta, 57, 79-87.
Barnes, S. J., Naldrett, A. J. & Gorton, M. P., 1985. The Origin of the fractionation of platinum-group elements in terrestrial magmas. Chem. Geol., 53, 303-323.
Boyle, R. W. & Jonasson, I. R., 1973. The geochemistry of arsenic and its use as an indicator element in geochemical prospecting. Jour. Geoch. Expl., 2, 251-296.
Crocket, J. H., 1979. Platinum-group elements in mafic and ultramafic rocks: a survey. Can. Mineral., 17, 391-402.
Jagoutz, E., Palme, H., Baddenhausen, H., Blum, K., Cendales, M., Dreibus, G., Spettel, B, Lorenz, V. & Wänke, H., 1979. The abundance of major, minor and trace elements in the earth's mantle as derived from primitive ultramafic nodules. Proc. Lunar Planet. Sci. Conf. 10th, 2031-2050.
Kazmi, A. H., Lawrence, R. D., Dawood, H., Snee, L W. & Hussain, S. S., 1984. Geology of the Indus suture zone in the Mingora-Shangla area of Swat. Geol. Bull. Univ. Peshawar, 17, 127-144.
Konstantopoulou, G. & Economou-Eliopoulos, M., 1991. Distribution of platinum-group elements and gold within the Vourinos chromitite ores, Greece. Econ. Geol., 86, 1672-1682.
Miller, D. J., Loucks, R. R. & Ashraf, M., 1991. Platinum-group element mineralization in the Jijal layered ultramafic-mafic complex, Pakistani Himalayas. Econ. Geol., 86, 1093-1102.
Mitchell, R. H. Keays, R. R., 1981. Abundance and distribution of gold, palladium and iridium in some spinel and garnet lherzolites: implications for the nature and Origin of precious metal-rich intergranular components in the upper mantle. Geochim. Cosmochim. Acta, 45, 2425-2442.
Morgan, J. W. & Wandless, G. A., 1979. Terrestrial upper mantle: siderophile and volatile trace element abundances. Lunar Plan. Sci., 10, 855-857.
Morgan, J. W., Wandless, G. A., Petrie, R. K. & Irving, A. J., 1981. Composition of the earth's upper mantle. l: Siderophile trace elements in ultramafic nodules. Tectonophysics, 75, 47-67.
Moritz, R. P., Crocket, J. H. & Dickin, A. P., 1990. Source of lead in the gold-bearing quartz-fuchsite vein at the Dome mine, Timmins area, Ontario, Canada. Mineral. Dep., 25 (4), 272-280.
Naldrett, A. J. & Duke, J. M., 1980. Platinum metals in magma tic sulphide ores. Science, 208, 1417-1424.
Naldrett, A. J. & von Gruenewaldt, G., 1989. Association of platinum-group elements with chromitite in layered intrusions and ophiolite complexes. Econ. Geol., 84, 180-187.
Oshin, I. O. & Crocket, J. H, 1986. Noble metals in Thetford mines ophiolites, Quebec, Canada. Part Il: Distribution of gold, silver, iridium, platinum and palladium in the Lac de I 'Est volcano-sedimentary section. Econ. Geol., 81, 931-945.
Page, N. J., Cassard, D. & Haffty, J., 1982a. Palladium, platinum, rhodium, ruthenium, and iridium in chromitites from the Massif du Sud and Tiébaghi Massif, New Caledonia. Econ. Geol., 77, 1571-1577.
Page, N. J., Pallister, J. S., Brown, M. A., Smewing, J. D. & Haffty, J., 1982b. Palladium, platinum, rhodium, iridium, and ruthenium in chromite rich rocks from the Samail ophiolite, Oman. Can. Mineral., 20, 537-548.
Prichard, H. M. & Lord, R., 1990. Platinum and palladium in the Troodos ophiolite complex, Cyprus. Can. Mineral., 28, 607-617.
Prichard, H. M., Neary, C. R. & Potts, P. J., 1986. Platinum-group minerals in the Shetland ophiolite. In: Metallogeny of Basic and Ultraba sic Rocks (M. J. Gallagher, R. A. Ixer, C. R. Neary & H. M. Prichard, eds.). 395-414.
Ross, J. R. & Keays, R. R., 1979. Precious metals in volcanic-type nickel sulphide deposits in West Australia. Relationship with the composition of the Ores and their host rocks. Can. Mineral., 17, 417-435.