Physiochemical, Bacteriological and Heavy Metals Assessment of Groundwater Quality Near Solid Waste Dumping Site
Keywords:
Investigation, Impacts, Fecal Contamination, Negative effectsAbstract
This study has investigated the impact of dumping sites on groundwater quality in Hazar Khwani, Peshawar, Pakistan. Twelve water samples were randomly selected, with four reference samples collected far from the dumping site and eight representative samples taken within a one-kilometer vicinity. These samples were analyzed for physiochemical parameters and fecal contamination. The results showed that mean values for pH, total dissolved solids (TDS), electrical conductivity (EC), total hardness (TH), chloride (Cl), and total alkalinity (TA) are from 6.13 to 6.83, 657.92 to 2392.2 mg/L, 696.91 to 2658 µS/cm, 394 mg/L to 1030 mg/L, 32 to 573 mg/L and 318 to 716 mg/L respectively. The mean concentrations of heavy metals for zinc (Zn), cadmium (Cd), chromium (Cr), copper (Cu), and nickel (Ni) were from 0 to 0.018 mg/L, 0.01 to 0.087 mg/L, 0.04 to 0.142 mg/L, 0 to 0.08 mg/L, and 0.02 to 0.09 mg/L, respectively. Total and fecal coliform contamination was found in 7 out of 12 water samples. The analysis revealed negative correlations between distance and TDS, EC, chloride, Cd, Cu, Cr, and Ni, with particularly strong negative correlations observed for Cd, Cu, and Cr. Depth was negatively correlated with pH, TH, TA, Cu, and Zn, but positively with TDS, EC, chloride, Cd, and Ni. Strong positive correlations were found among TDS, EC, TH, and chloride, and between Cd-Cu, Cd-Cr, and Cu-Cr. Negative correlations were seen for Cd-Ni, Cu-Ni, Cr-Zn, and Zn-Ni. The samples that surpassed the Pak-NEQS and WHO limits had 75% TDS, 58% TA, 8% Cl, 42% TA, 92% EC, 67% Cd, 67% Ni, 83% Cr, and 58% bacteriological contamination. To reduce any negative effects, waste disposal should be properly monitored.
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